Current trends on dry photocatalytic oxidation technology for BTX removal: Viable light sources and highly efficient photocatalysts.

One of the main gaseous pollutants released by chemical production industries are benzene, toluene and xylene (BTX). These dangerous gases require immediate technology to combat them, as they put the health of living organisms at risk. The development of heterogeneous photocatalytic oxidation technology offers several viewpoints, particularly in gaseous-phase decontamination without an additional supply of oxidants in air at atmospheric pressure. However, difficulties such as low quantum efficiency, ability to absorb visible light, affinity towards CO2 and H2O synthesis, and low stability continue to limit its practical use. This review presents recent advances in dry-phase heterogeneous photodegradation as an advanced technology for the practical removal of BTX molecules. This review also examines the impact of low-cost light sources, the roles of the active sites of photocatalysts, and the feasible concentration range of BTX molecules. Numerous studies have demonstrated a significant improvement in the efficiency of the photodegradation of volatile organic compounds by enhancing the photocatalytic reactor system and other factors, such as humidity, temperature, and flow rate. The mechanism for BTX photodegradation based on density functional theory (DFT), electron paramagnetic resonance (EPR) and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) investigations is also discussed. Finally, the present research complications and anticipated future developments in the field of heterogeneous photocatalytic oxidation technology are discussed.

Boosting photocatalytic CO2 conversion using strongly bonded Cu/reduced Nb2O5 nanosheets.

Green energy production is becoming increasingly important in mitigating the effects of climate change, and the photocatalytic approach could be a potential solution. However, the main barriers to its commercialization are ineffective catalysis due to recombination, poor optical absorption, and sluggish carrier migration. Here, we fabricated a two-dimensional (2D) reduced niobium oxide photocatalyst synthesized by an in situ thermal method followed by copper incorporation. Compared to its counterparts, pure Nb2O5 (0.092 mmol g-1 CO) and r-Nb2O5 (0.216 mmol g-1 CO), the strongly bonded Cu/r-Nb2O5 (0.908 mmol g-1) sample produced an exceptional amount of CO. The separation of charge carriers and efficient use of light resulted in a remarkable photocatalytic performance. The acceptor levels were created by the Cu nanophase, and the carrier trapping states were created by the oxygen vacancies. This mechanism was supported by ESR and DRIFT analyses, which showed that enough free radicals were produced. This study opens up new possibilities for developing efficient photocatalysts that will generate green fuel.